The FSB may very well be true to the barrel, and the canting due to the assembly method. If a barrel nut is tightened while the barrel is held by a reaction rod, or barrel clamp, there can be a tendency for the upper receiver to rotate slightly to the left. When the barrel nut is tightened while the upper receiver is held by a clamshell, or similar device, there is a tendency for the barrel and FSB to move to the left. In either case it is due to the index pin compressing against the side of the slot, and if overly torqued can actually indent the slot. I'd be willing to bet if you broke that nut loose and clamped the receiver and torqued it back down the FSB would move to the left, perhaps enough to square it up.