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So you think 35% would be a good setting or is that to low?
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That would probably be fine. Remember, the sensor on the dehumidifier is sampling air that exits the unit, not the room as a whole. I would not depend on it. Instead, place several hygrometers throughout your vault to get a better sense of the overall environment and adjust your dehumidifier controls accordingly.
Personally, my dehumidifier is a bit undersized for my "man cave". However, most of the year I do not need it. When I do, I let it run full bore until the weather changes. My indoor Rh varies from twenty
something percent in Jan/Feb to forty
something percent in the dog days of August. I have never had a problem with rust
or damaged wood.
ETA- Good guns are built pretty hearty to begin with. A good rule of thumb is that if the environmental conditions are comfortable for YOU then it is probably OK for your guns. If it feels humid to you then you probably need to do something about it. Also, keep a thin coat of oil on the metal and use a good wax on the wood every once in a while.