Tritium is a very interesting, an isotope of Hydrogen. The glow comes from the decay of Tritium, with a half life of 12 years. Meaning after 12 years, the glow will appear to be half as bright. I have a set of Trijicon night sights on a Sig 229, purchased new in 2006. The box had 2005 marked by the dealer, so just the pistol alone is approaching 10 years, the sights were more than likely older.
The sights are dim, can still be seen, but I can see they will need changing next year.
As far as acclimation to darkness, 15 to 20 minutes is the typical norm, to get the full effect and range of brightness of the Tritium sights.
I took some nuclear engineering courses as electives in college and even after 33 years, I still remember the details, it was very interesting
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