It probably wasn’t copper.
Copper generally is pretty tenacious and has to be removed either chemically (using a bore cleaner like Shooter’s Choice or Sweet’s) or with an abrasive (such as Remington Bore Cleaner or J-B Paste).
When removing copper chemically, your patches will come out with a blue-green tint.
Copper in the bore is pretty hard to see, except for maybe a little at the very muzzle end of the bore. It appears as a length-wise copper colored smear, often along the top edges of a land.
Some Oly barrels aren’t chrome plated, so you actually might have had a bit of rust.
Break-Free is a good protectant, as are many other products.
If you want to give the bore a heavy coating of a protectant, be sure to apply it with a fairly [b]loose[/b] patch. A tight patch tends to squeegee fluids out of the barrel. If you give the bore a heavy coating of a protectant, run a dry patch through the bore before shooting to remove this.
You might also want to consider where and how you’re storing the AR. If you’re keeping it in an airtight case, you might be getting some condensation. You might also be keeping it in a humid location or (while pretty unlikely) around rust causing chemicals.
When you remove rust from a bore, you still have pitting that cannot be removed. If you catch the rust in time, the pitting will be very small (to the point of not being visible) and really shouldn’t be a problem other than requiring more cleaning than normal.
Incidentally, also make sure to clean out the chamber and give it a good coating of a protectant. A rusty or pitted chamber can cause functioning problems.
Hope this helps!