If the bolts are good quality (and his is from a Bushy M4, which is a relatively recent model), and not worn out, it will work just fine in both barrels.
Kabooms do not happen from excessive headspace.
While we are quoting manuals and such, I refer you to Armalite Tech Note #11:
"There are a number of popular misconceptions concerning headspace, notably that the tighter the headspace, the better, that loose headspace is dangerous, and that one particular dimension is best. None of these common beliefs is totally true."
"Insufficient or excessively tight headspace tends to cause malfunctions such as failure to lock. It often makes extraction difficult and can cause dangerous stresses on the mechanism that shorten its life expectancy or lead to failure. Excessive headspace may lead to gas leakage around the case or head separation and the sudden release of high-pressure gas. Most shooters fear excessive headspace, but it is actually insufficient headspace that is more dangerous. A good firearm design can actually tolerate a great deal of excess headspace."
"While the SAAMI example above demonstrates that a fairly wide range of dimensions work, manufacturers narrow their tolerances to conservative ranges that allow a reasonable combination of safety, reliable function, accuracy, and useful life."
For SW99 to have a kaboom from swapping bolts would be less likely than winning the Powerball. If a kaboom occurs, it will usually be from a high primer, or other ammo related problem, not from the rifle.
The best deteminant of proper headspace is to examine fired brass for shiny rings just above the case head. Those rings are signs of the case stretching.
I have about 30 years experience with handloading, and about 40 years experience shooting firearms of all types. As a child, we had to clean the reloading gear off the kitchen table to eat dinner at night. There were haybales in the front yard (about an acre) where Mom shot archery, and we shot clays every afternoon out back, and shot at the skeet club on Sundays.
I have enough years of experience with the AR15, shooting and building them, that I make the statement with full confidence, yes, he can even swap bolts.