As others said it's a pretty small library at the moment. Next spring things will look a lot better. IMO:
Ass Creed 4
Tomb Raider Definitive Edition
Wolfenstein New Order
Watch Dogs
Infamous Second Son
Also, a couple of smaller titles to check out:
Resogun
Outlast (horror game)
Transistor
All of those are primarily or solely single player games, so if you really want that MP fix, I guess pick up Battlefield 4 or CoD whatever number they are up to now. BF4 is still a buggy mess last time I checked, and the latest CoD is the most mediocre one in years. Neither is anywhere near as good as their predecessors, IMO.
I personally thought Killzone 4 was meh - pretty game, but kinda bland in the story and gameplay. Multiplayer was decent. Watch Dogs doesn't do much for me either TBH, but a lot of others seem to like it. I'd pick up the others first though; WD just came out so it's still full-price. Some of the others I mentioned have dropped in price.
Of all the ones I listed, if you haven't played Tomb Raider yet I'd go with that one. It came out early last year so it's not a brand new game, but it was easily one of the best games of last year, and it looks great on the next gen systems. Plus, it's cheapish these days. Amazon has it for $40.
If you've already played TR, then Wolfenstein would be my second pick. Also a great game. It's a new release though, so it will be full price or close to it.
ETA: The Last of Us, one of the best games to ever come out on the PS3, is being up-res'd and ported to the PS4. I think its coming at the end of this month? If you haven't played it yet, I'd highly recommend that one too.