What exactly do you want to know? I'm not one, but I worked closely with some and still keep in touch with a couple once in a while. They were Air Force, but with K9 handlers (the leo ones anyway) you aren't just part of your own branch of service, but are part of the DoD in general. As in where I worked with them, when I first got there, the kennel master was Army, most of the handlers were Air Force, and some were Navy. Just sort of depends on who is available. All of the training after Initial Entry Training/Basic whatever the name of the week is, is done at the same place with instructors from all branches.
There is a wide range of jobs that they do, from sniffing for bombs and drugs, to the attack training. Most of the dogs are pretty much generalists, though some only have the temperament for a specific task. The Army also has a few used by Enigneers for mine detecting, and not law enforcement. From what I heard, it's a pretty tough school. LOTS of attention to detail, and learning how your dog acts, and it's attitudes and personality in general.