The metal of the barrel has little or nothing to do with kB's. Any gun can kB in certai circumstances.
The Glock with it's partially unsupported barrel in the 6 o'clock postion (to aid in feeding) is possibly more prone to a kB is the pressures is high enough.
If you shoot lead, and do not clean out the barrel properly you will raise pressure. You you shoot a really hot load you will increase pressure.
I have seen heard a few first hand accounts of kB's. One involved a 1911 type gun, the other was a Glock. The Glock was shooting major power factor 9mm rounds (done on purpose for whatever reason). The gun kB'ed twice. The shooters top web of his hand had a deep tissue bruise. The gun after 2 kB's was fine.
For those that don't know in IPSC pistol competition shooters strive to make their reloads make "major power factor". Which is bullet weight x feet per second/1000. Major power factor is 165. It can be done in the 9mm for the the compensated open division guns. This particular gun that kB'ed was not a open gun, but a regular glock 34 with no compensator. It did have a fully supported aftermarket barrel (barstow). Just goes to show that the partially unsupported barrel is a factor, but not the only factor in a kB.