Cutting the heads for larger(oddball sized)valves is usually a race only type thing and usually an in the white(using gun terminology) head is used that still needs quite a bit of machine work. Cam would help as long as you don't go too large then you gotta start replacing everything else to make efficient use of the cam. Rebuilding would obviously get it back close to stock ratings. Throw in a very mild street cam and I think it would make a noticeable difference. Swap the exhaust, run a mild intake and rejet the carb and make the ignition slightly hotter probably be a good little runner.
One thing to think about is if you run a pretty hot cam, then you gotta upgrade the fuel system, improve the flow on the intake and exhaust side to make use of the larger cam. You end up with a boggy dog because it either can't get the fuel to it fast enough, feed it enough fuel, or get the burnt fuel mix out of it quick/smoothly enough. Would have to run a hotter ignition to get a good clean/thorough burn of the increased fuel mix. Just food for though. Keep it simple and not too radical and it'll perform great. Biggest mistake most people make is throwing an entirely too large cam into an engine without getting everything else up to snuff to use the profile of the cam to it's potential.