I'm mostly a 3ds MAX, and more recently Rhino guy. You should be able to hit a few primitives modelling videos and get going on that. What I see of that choochoo building is mostly primitives.
Depending on how big the printed model is, you might have trouble getting some of the smaller pipes and stairs. I'd load those images on a texture plain, front and left, or do a viewport background, or whatever they do in Blender, and use that, those images are totally serviceable for that purpose.
Do you have any 3d printer experience? Great thing is, your model doesn't have to be of great technique, or water tight, low poly, or just general good. You're going to lose some dimensional accuracy in the print anyway. You can bash them primitives together and go. You're probably looking at printing that think out in several pieces and then gluing them together.