Most of the info and a past event are in this twitter link
Launch webcast for 200 PM EST launch on 21 January 2022
Jan. 21 Live Broadcast: Atlas V USSF-8
The circularization burn is scheduled for 6h31m after launch, with separation of the satellites at 6h36m and 6h45m after launch.
The fuel dump should be at 9:11 PM EST and look like the following:
For an on time launch here is where you want to look. Binoculars may help. This is just west (to the right) of the constellation Orion. What about launch delays? For every four minutes delay, Orion will move one degree closer to the ovals. The ovals stay stationary using azimuth and elevation. Your fist from thumb to pinkie at arms length is roughly ten degrees. Obviously be out early. Fifteen minutes or so helps to adapt your eyes to the darkness making it easier to see this event.