There is no bolt hold-open on the SLR-95. The button just before the start of the stock is the retaining button for the topcover. The button is attached to the recoil spring guide and therefore one end of the reciol spring (operating spring) and the other end of the spring pushes against the bolt carrier.
What can happen is that the bolt carrier can hang on the hammer if you fiddle with it. It's easier on low round count guns, as there's still finish left, no wear, etc. On higher round count guns, it's difficult or impossible to get it to do it.
Odds are if you were pushing the button while manually pulling the bolt back, the bolt wouldn't be allowed full travel and stop right where it would need to be to get hung up on the hammer. As you shot it and the gun broke in, it no longer will hang up there.
Most AK variants just don't have bolt hold-opens, and the SLR-95 is one of those. As you found out, it's dangerous to try to use a bolt hold-opne that isn't there.
Personally, I like bolt hold opens, but they are not on many weapons: HK MP5, HK G3, L1A1, M1 Carbine, open bolt SMGs like the Thompson, MP-40, STEN, Grease Gun, PPSH-41, etc., other open-bolt guns like almost all MGs. None of these have them. Quite frankly VAST majority of proven combat small arms have no bolt hold-open when empty. It's a nice feature, but not required.
Ross