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AR15.COM
3/15/2008 8:08:21 AM EDT
Just curious. Do solids have a pH level, or does it only apply to liquids?
3/15/2008 9:09:41 AM EDT
[#1]
in some instances yes.

a easy way to explain this is to research "soil ph" on wikipedia . that should help you some
3/15/2008 9:10:20 AM EDT
[#2]
Sort of. Zeolites are called "solid acid catalysts".
3/15/2008 9:12:01 AM EDT
[#3]
Yes.

Look at lye.

Look at citric acid (the sour stuff on candy).
3/15/2008 9:13:07 AM EDT
[#4]
It's been a long time since chemistry, but can't it only be acidic/basic when the hydrogen ions become dissociated?  Doesn't that only happen in solution?
3/15/2008 9:20:22 AM EDT
[#5]
TUMS antacid....
3/15/2008 9:22:31 AM EDT
[#6]
Sodium


eta Just looked it up. Alkali metals. Alkali salts, acid salts.
3/15/2008 9:26:46 AM EDT
[#7]

Quoted:
Just curious. Do solids have a pH level, or does it only apply to liquids?


No, pH refers to solutions.  Here's a dumbed down explanation.

PH refers to free H or OH molecules in solution.  If you have a lot free H ions then it's acidic, <7.  If you have a lot of free OH ions it's basic, >7.

When you put a solid into liquid it will release it's H or OH ions to create the pH.

If you put Sodium Hydroxide into water the Na and OH will dissociate.  Sodium has a charge of +1 and Hyrdoxide has a charge of -1 so they are held together by an ionic bond which is weak in comparison to a covalent bond.  

So, the charges dissociate and are no longer ionicaly bonded.  Now there will be an excess of OH ions so you will have created a basic solution.  If you put 40 (NaOH's molecular weight is 40) grams on NaOH into water and bring the volume to 1L you will have made a 1 Molar solution.  You can pH the solution and determine its basicity.  If you then add more water you will have diluted out the OH ions so the pH will then drop down from where it was at.

If you simply stick a pH probe into NaOH granules it won't give you anything meaningful.

Soil pH is tested using water or the water existing within the soil.
3/15/2008 9:38:50 AM EDT
[#8]

Quoted:
Snip


Kind of scary that I still remember chem from 10 years ago.
3/15/2008 9:48:32 AM EDT
[#9]
I was beat to it, but yeah, only in solution with water.

However, since a good 70% of our mass is water, you probably shouldn't be putting solid NaOH in your mouth or breathing HCl vapors.
3/15/2008 9:52:37 AM EDT
[#10]
A solid can be eager to give up or take in hydrogen ions when it is put in solution, but it doesn't have a pH in the usual sense on its own.