.22 Ammunition may have a larger proportion of glass in the priming compound (used as a sensitizer to cause primer ignition on impact). As a result, the high-velocity spray of particulates tends to be abrasive - heavily used .22 barrels show a pronounced area of erosion at 6:00 just forward of the chamber.
I've heard of people using the following to clean firearms:
- Automatic transmission fluid
- "Kroil" brand penetrating oil
- Straight kerosene
All of these have on thing in common: they are extremely light fluids, and penetrate under the layer of fouling. Could be wrong, but I think both WD-40 and Hoppe's #9 incorporate kerosene in the formula.
The newer generation of petroleum-free firearms cleaners show a lot of promise. I use MPro-7 (also sold as Hoppe's Elite, and some Smith & Wesson product), and there are increasing number of similar products. The stuff works well - following a 5 minute soak, crusted carbon residue wipes off. Note that MPro-7 is a powerful degreaser, so some application of sort of preservative oil is recommended after using it.
Not sure how Simple Green compares to MPro-7, but they're both cleaners, and effective oil removers. Perhaps diluted Simple Green is in order?
Competive analysis of MPro-7 vs other products may be seen at
www.mp7.com/NCompetative.htm