Black powder isn't very difficult to make. People used to make it at home at times or in a pinch. Quality control is the problem with that. BP is sulphur, saltpeter and charcoal, in the right proportions. Most modern powders are a formula of nitrocellulose, which is more difficult to make.
Black powder, and black powder fouling/residue is VERY hygroscopic, and contains lots of salts. Failure to quickly clean a barrel after shooting can lead to very serious rust, very quickly.
I load black powder cartridges, and they're very similar to modern cartridges. I use modern cases and primers, with cast and lubricated bullets. Black powder is sensitive to how it settles in the case, and how it is compressed. Some black powder works better with some or a lot of compression, and some does not like to be compressed at all. Compression doesn't have much affect on pressure as it does in smokeless loads. Most black powder cartridges will also have a wad over the powder in the case. Some people actually still paper patch bullets, instead of using grooved, lubed bullets. To each his own.
Black powder shooting is very fun and satisfying, and the sport of competition in BPCR is growing. Check out the forums, and the site, at
Shiloh rifle company.