The bead and base on the barrels are not screwed on, they're brazed on and are a MAJOR PITA operation to get off.
You have the option of heating the barrel to a red heat to melt the high-temp brazing, or cutting the bead and base off.
If you heat, you run a risk of damaging the barrel, and it will require re-polishing the inside of the barrel, and refinishing the outside.
Cutting the bases will leave a bare spot, which may be covered by the new sight, or it too will require a refinish job.
After you get the beads off, you have to braze the new sights on, or drill and tap for screws.
Drilling for the front requires trimming the screws inside the barrel, since they will be too long, and this also requires polishing the bore.
Here's some options.
1. Just buy new barrels with luminous sights already installed.
I assume Remington sells Police barrels already with the sights, and the Police will fit the Express.
2. Buy the Wilson type front sight that is epoxied OVER the front bead's base. The Wilson company installs these with epoxy AND a cross pin to hold it tight.
The problem here is in mixing different manufacturer's sights, which may not be compatible on height.
My advice: Cut the bead sight off the barrel. This is less risky and doesn't require a refinish.
I use a jeweler's "wire saw" or a GOOD hacksaw to cut as much off as I can WITHOUT scarring the barrel.
Then I use a bench grinder to take it close, again being careful not to scar the barrel, then finish with hand files.
This works well, and you'll have to do the filing anyway to remove the brazing even if you use heat.