Yes. The older slides are stamped steel while the newer slides are milled (one solid piece). You can tell by looking at the roll pins in the slides. One solid roll pin means milled, two pins (one inner and out outer) means stamped. However, I have owned several of both and can tell you there is no difference in the performance of the pistol.
Other than that, the "W Germany" marked pistols are excellent quality and sorta fun to have given the history behing the "W". You might also look for other interesting marks on the slide. For example, my P226 has "Interarms" marked on the slide. They were the first importers, so I have one of the original P226s that came into the country. Another interesting mark is "Tyson's Corner" which is the old location of Sigarms who are now in Exeter, NH.
So, go ahead and pick it up. You will love it.