You didn't mention what kind of ammo you were shooting. Sounds like an ammo issue to me. Reloads that are loaded too lightly can also give you the same problems. If carbon build up is keeping you from chambering rounds, then I would guess you do not have a nato chamber and should not be shooting surplus through it.
That all said, some brands of ammo are just dirty. If you want to keep shooting the same ammo, just live with it.
Also make sure the chamber is free of lube before shooting since that will lead to carbon build up in the chamber as well.
Edited to add: Doubt it is your gas rings giving you problems. If the bolt doesn't slide out of the carrier under its own free weight, your rings are fine. Don't worry about rings being lined up, it doesn't matter, ignore the TM on this.