A barrel extension wrench is for removing and installing barrel extensions.
Tweaking front sights into alignment is usually going to require very little movement.
Sometimes, simply loosening the barrel nut and holding the sight the direction you need to move it while re-torqueing the barrel nut will fix it.
Make sure to grease the front of the barrel extension flange so the barrel nut torques against the grease and it will not force the barrel to move as you torque the nut.
Very few people putting together AR-15's have a legitimate need for a barrel extension wrench.
As I specialize in BUILDING AR barrels, I obviously use one every week, but there is no need to remove extensions otherwise.
During the process of building a barrel, the extension gets torqued into place and then the pin is installed.
The gas port is drilled at TDC as determined by the indexing pin.
Moving/swapping the extension is almost always going to change the reference and the gas port/FSB is not going to be TDC anymore.
For you non-mechanic types, TDC=Top Dead Center, a term used when working arond engines, usually the crankshaft position where cylinder #1 is at the exact top if it's travel in the compression stroke. In the case of barrels, you can think if it as 12:00.