It mostly has to do with the materials used. Also, some stocks (like the Vltor) aren't standard designs, meaning that someone had to first design it, and then produce it. Making a standard CAR stock is much easier since the design is already done. It's always cheaper to copy than to create something new. The Vltor offers a lot of improvements over a standard CAR stock, and is priced compareably to a new Colt stock (maybe even a little cheaper).
That said, the collapseable stocks made by RRA, Bushmaster, etc., are essentially copies of the original Colt design, but are made of very high quality materials, and can be had for around $75 complete if you shop around a little. It's sort of like tools - you can buy Snap-On which are high end and probably the best, you can buy cheapo Taiwan stuff that may work a few times before it breaks, or you can buy Craftsman which is priced somewhere in the middle, but is of high quality and still has a lifetime warantee.
ETA - there are huge differences in strength between various plastic materials. The stronger stuff usually costs more money and can cost more to manufacture into a finished product. The best way to demonstrate it is to have the two stocks in front of you, side by side. It will be VERY easy to tell which is the cheapo.