Remember, two hard drives in RAID 0 will not double your access/read times. A more realistic increase will be about 50% over a single drive. If you want to boost your speed, I would go with the Western Digital Raptor series. They're 10,000 rpm, 8mb cache and they have a 36 and a 72 gig version. The 72 gig version is slightly faster due to some new command queing stuff. I believe the 72gb is at 4.5ms access time, and the 36gb is 5.3 if I remember right. Compare that to what is typically in the IDE/SATA market.
The 36 gig is about 110 dollars at Newegg, and the 72 gig is about 178'ish. Both have 5 year warantees too, which is outstanding.
I would recommend taking a look at what Abit has to offer in terms of motherboards. I've found their stability to be very good, and they have a very active BIOS revision program.
I personally have two of the 36gb Raptors in a RAID 0 on my computer, and they are very fast. I recently built a clients computer with two of the 72gb versions, and it was smoking with a large amount of disk space.
When you build a RAID0, it combines the two drives total space, so you can make some big drives very quickly.
Make sure you have access to the internet during your build, since this is your first. You'll want to be able to ask for help or do some driver downloads. Establishing a RAID is a little trickier than just a singular drive. I would recommend writing the stripes at 128kb for typical computer use. You need the RAID controlers drivers on a floppy and have to press F6 during the very beginning of the Windows installation. Don't do the quick format once you get the windows files loaded. Let it do the thourough one on NTFS. NTFS segments of 4kb (this is the default.)
Make sure the motherboard you pick has a bootable RAID device. That is, if you want to install windows to your RAID aray.
A common misconception is that the RAID will increase frame rate on games. A RAID has very little effect on this type of action. What you do notice with the RAID is quicker load times, faster response from the system.
The idea of moving the pagefile to another drive would work if you set up yet another RAID to house it. This is where a major bottle neck starts. The Southbridge or the PCI bus is limited on the typical 33mhz PCI bus. You have all your other components talking on these channels too.
This is why having a RAID0 doesn't give you a 100% increase in performance. It gets worse as you add more drives to the mix. Having 4 drives will be about 75% faster then only 1 drive -- access time will be increased though.
I've been waiting for the PCI 66mhz bus to come to the desktop arena. This would double the bandwidth in which you could get the hard drives going. All data I have seen though indicates that it only really shines when transfering large data files. PCI-express has some hope though in the future.
If your system has a lot of memory, 512mb - 1024mb, the pagefile isn't used as heavily. You know when it gets used though, since you start hearing the disks thrashing, and performance goes out the window. I have 1024mb in my computer, and I am reading up on simply disabling the pagefile. While running a bunch of programs like 3dsmax, netscape, winamp, emule, and probably 35 running strings, I only end up using about 600 megs of memory. During Doom 3 loads, it goes to about 500 megs, then once in the map it drops back down to around 250.
Another good thing to do is get an aftermarket disk defragmenter. The one that comes with Windows could be considered the lite version. I use perfect disk 6.0, and I am very happy with it. It is just as easy to use too, so no fear of running into option city.
Post the rest of the spec's on your computer you're putting together. What is going to be the purpose of the system? High end games, web surfing, ect..
-Steve