Dont worry about the chamber. It simply understated, is a hybrid of SAAMI and NATO.
It's not the bullet weight that I have found that affects grouping at 100yds, as much as it is the quality and consistency of the components, and the cartridge as a whole.
FWIW, I have found three cartridges to be very successful in the RRA 1/8 Varmint upper:
Black Hills Blue box 68gr (50ct)
Black Hills Blue Box 52gr (50ct)
Wichester White box Varmint 45gr (40ct)
All of these group right at 1" all day long. I have had trouble getting sub MOA reliably, but have had a few .75" groups and one .5" grouping.
I would like to try some Federal gold medal match. I hear this barrel likes 69gr sierra's. Dont know yet.
Best ammo of course is going to be a handload worked up for your particular rifle.