I would take the rifle apart (barrel out of stock) and secure it in a vise pointed in safe direction and with some sort of improvised bullet trap. Then I would carefully remove the nipple from the breech and see if I could determine if any powder is present in the barrel by carefully inserting a small pick in towards the chamber. You mentioned that the rifle would not fire earlier. There may only be patch and ball, no powder..... Next I would pour in a decent amount of oil and let it soak into the breech/chamber. After a couple of days, I would very carefully to use a BP bullet puller, and see if I could remove it.
There are two alternative methods that might works also.
A. Using a CO2 shot discharger, sold by Mid Southshooter supply, Midway etc. screw it onto the nipple push button with rifle pointed in a safe direction, then verify clear chamber. Clean thoroughly and put it back into service (if you are a BP shooter)
B. Depending on the method the barrel was built, it may be possible to put the barrel in a vice (as above) and unscrew the rearmost portion of the barrel aka the breechplug. If you can do this then cleaning is like for any normal breechloading just using proper solvents for BP.
IM/Email if you have any questions, I'll try to help.