I think the key is to leave the extended ramp a little "proud" of the barrel extension ramp. What I mean by this is that don't grind down the extended ramp to be perfectly flush with the extension ramp, leave it a little bit higher. That way, if there is any wearing down of the bare aluminum, it hopefully won't wear down below the extension ramp thereby creating a ledge for bullets to snag on.
I agree with Tweak that corrosion isn't really an issue with aluminum since it will most likely be coated with lube that has creeped out of the extension. Even if it does corrode, the oxide created is going to be tougher than the bullet jacket material. There is a reason sanding paper is made from aluminum oxide. Plus, the oxidation of aluminum is self-limiting (well unless some sort of galvanic action is going on like Tweak mentioned), it's not like steel whereby it will continue to oxidize even after a surface layer of rust has formed.