Ammunition is sometimes difficult to understand as there is no real fixed way to name a cartridge. Here are some other odd ones I forgot on the first reply:
7mm/08 a .308 cartridge necked down to accept a 7mm bullet
35 Whelen a 30/06 cartridge necked up to accept a .35 caliber bullet
Anything with WSM after it stands for Winchester Short Magnum, a group of cartidges that are short action sized but still pack a punch (in simple terms)
And hundreds more!
As for which is the best, well that is a loaded question. That depends on a ton of factors. What kind of gun are you going to shoot it out of? Do you want an assault rifle type setup or a bolt action or a lever or what? If you are looking for a first hunting gun I would have to vote for a 30/06 bolt action. The 30/06 is able to be used in many different ammuntion setups. You can shoot a 110 grain varmint bullet all the way up to around a 200 grain bullet for larger game. A gun of this type can be used to hunt for a very wide range of game and can shoot fairly flat with minimal to moderate recoil. However a bolt action rifle is not much for self defense so if you want a truly all around gun here is my suggestion:
AR-15 chambered for .308 (AR-10) made by any high quality manufacturer. Add to it a variable power scope that will also allow you to use your iron sights as well.