Ok, Since I probably have contributed to some of this confusion, I thought I might chime in here...
I spent 3 years as an ER doc, during which I got to see people killed, maimed and generally fucked up with all manner of guns, knives, chainsaws, bottles and just about anything else you can think of. Our species is VERY adapt at hurting each other.
That being said, NO hand gun is a great killer of people --- Period, sorry guys. Hand guns kill via hemorrhage. Notice I said KILL, not stop. You can 'stop' someone by hitting their spinal column or their brain stem. Again, Stop does not equal Kill. Hemorrhage requires that A.you have a round that penetrates deep enough to hit something that bleeds (alot if you want them dead quick)B. after it(the bullet) gets there it is capable of doing the required/desired damage to get the bleeding started.
It is generally assummed and I believe rightly so, that the more muzzle energy = more penetration. However, Penentration is not the only requirement, we also need to do damage when the round gets 'there'. This is why we use HP/prefrag/etc ammo -- Bigger hole/more missles = higher chance of hitting something that bleeds and making a bigger hole in it.
So to answer your question: You can kill people with both. A 32 with FMJ MAY actually have less muzzle energy than a 22lr. If the energies are equal you should go with the 22 - more rounds, and less surface area will give you more penetration and more liklihood of hitting something vital. If the 32 has more muzzle energy use it. Remember, you need to know the velocities out of YOUR pistol not what the factory says.
As an aside, STAY AWAY FROM .25 autos - they have about 1/2 the energy of the 22 and I have seen way more pissed off 'victoms' of 25 shootings than fatalities. In fact most of the time the shooter is the one that gets admitted since the shootee beat the shit out of 'em.