Quoted: You're right, I am using gas fireplaces but the humidity levels in the room are above the norm. I have some Walmart thermometer /humidity meters that read above 75% humidity in the room. Sometimes it is above 90% in the winter.
The allergist said that is too high and to get a dehumidifier
So it's definitely not the water heater?
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You have gas heat and you still have humidity that high? Where do you live?
I personally do not see how it could be the water heater. I would think like some of the others have suggested, it could be the water itself. If you are concerned, have it tested.
Most, if not all, hot water heaters have tanks of either fiberglass or some other non toxic metal. Unless you are allergic to some of the other metals used, maybe but then again I would think you still would see it year round. But then again, I'm no doctor, nor do I play one on TV.
Have the water tested and go from there. You may end up replacing a perfectly good water heater and still have the same problems. Go with the cheapest fix first.