For what it's worth, I am a CPA, but though I've studied tax regulations thoroughly, my professional focus is in accounting. So I highly recommend talking to a local CPA that does taxes full-time. Spending a couple hundred dollars now can save you a huge headache later.
However, I do have the following thoughts about your situation:
Claiming part of your personal property as a business expense is tricky and can often be a red flag that triggers an IRS audit (mainly because so many people don't do it correctly). You've got to have proper documentation showing the total expense and then allocating out the personal and business percentages. The easiest example is if you have a 3000 sqft house and run a business out of one room that's 300 sqft, then you can allocate monthly expenses (like electricity) to it using a 10% ratio. I would think the same concept could be applied to multiple buildings. Though it would be easier if you allocated the entire barn to the business and sub-metered it for utilities.
As for the actual purchase price, I'd recommend checking with a full-time tax professional. Businesses have a set depreciation schedule for their assets, which is normally accelerated (so you get the most in year 1 and then it declines in each subsequent year). Because it's co-mingled with personal property, you'd have to make sure and allocate everything out between the two (i.e. what's the value applied to the barn versus the main house in the total purchase price). Also keep in mind that this effects both sides of the equation. Mortgage interest, for example, would get allocated between personal and business, so only part of it would go into your personal itemized deductions and the rest would hit the P&L of the business.
Another thing to consider is that the property is correctly zoned. I'm not sure where you're looking at moving to, but I'd check that running a business out of the home is allowed. Otherwise your first federal tax return would be evidence against you in a local lawsuit.