The binos are all around better, especially if you plan on using them for any length of time, but you can use the PVS14 for more things off your head. Attach it to a telescope, spotting scope, your phone, carry it in your jacket pocket, etc.
You will want binos about 15min after using your PVS14. The '14 is a good place to start.
To add some rational logic here. You can get a '14 for $3k-$5k. binos are $6k-$15k. How much are you actually going to use them? Even if just for novelty, what kind of area do you live it; Really rural, binos would be cool. Urban, binos not so logical. When I go play with mine around my home I want to get rid of every streetlight on my street.
Binos are unequivocally a better experience, but the price is steep.
ETA: I’m for getting both fwiw. Learn on the ‘14 while you save up. Then when you have the binos you can use the ‘14 for more under the radar stuff or hand it off to someone. It’s small and handy. You pretty much need a helmet with binos, with the ‘14 you can use a nightcap (which is worth having.)