Quoted: A detailed answer to your question can be found in "The Great Rifle Controversy" by Edward Clinton Ezell.
I read this about 10 years ago and my recolection is that the initial issue of M-16s were sent with the wrong ammo (contracted lot was loaded with ball powder, rather than the IMR powder Armalite specified) and with no cleaning equipment. Some desk bound buracrat in Washington (D.C.) had heard the AR-15 didn't need to be cleaned.
The above was a recipe for failure if ever there was one.
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SS109, it took until about 1968 to get things worked out with the M16. The cost of this delay was measured in dead Americans.
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DaveT has got it right.
"..............and then someone in the military changed the 5.56mm ammo powder from IMR to Ball powder. They did it
without tests or checking with ArmaLite or even notifying Colts' who, of course, continued to fire the acceptance tests with IMR powder. Colts' didn't learn about it until they read in the newspapers that all the M16's in Vietnam were jamming, one Marine unit had been overrun, and everyone killed because their M16's jammed."
Field investigation found that the
guns were all jammed by a fired cartridge that had failed to eject and that none of the dead had a cleaning rod to clear the jam.The above from an interview with James Sullivan February 2001. (James Sullivan and Bob Fremont designed the AR-15.)
Now:
The chamber was not chromed at this point...
No cleaning kits issued...............
The Army had 100 million rounds of Ball powder on hand.................
(For any historians out there see the "Ichord Committe" report on this disaster.)
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Even today, Ball powder is not compatabile with the M16 design.
Ball powder:
fouls the gas system and wears out the piston rings...
Ball causes the cyclic rate to speed up resulting in light strike misfires from bolt carrier bounce................
Failures to extract...............
There's been a bunch of work-arounds to make the M16 function with Ball.
Part of this crap goes at the feet of the Army, some to that all time idiot McNamara.........