The bolt heads on Enfields are numbered. What number is yours? It is stamped on it, and might be faint but it is there you just have to look for it.
.303 ammo headspaces on the rim if I am not mistaken. It does not sound like you have excessive headspace, but too tight.
If I remember correctly if it is too tight you will have to go down a number. I may stand corrected on this, so if anyone knows correct me. So, say you have a #2 bolt head, get a #3.
The bolt head screws right out of the bolt, as I recall.
*Disregard* all the above. I misunderstood you. Do you already have the rifle or are thinking of buying one? If you are wanting to buy one I seriously doubt any seller is going to allow you to remove the extractor in order to check it. However, if you do buy one and the headspace is off, refer to the above on how to correct it. As I remember, there are bolt heads marked 1 through 5 for the Enfield.