you shouldn't have to oven cure "rattle can" paint. Just clean (degrease) it and spray it on. Read the directions on the side of the can.
If by mag well you mean the entire lower of an AR, removing parts such as the grip and stock is a little bit more tricky than just unscrewing the screws. There are springs, detents, and catches that are held in place by the grip and stock. I suggest you browse your manual and become familiar with all the parts and pits in the gun before you start removing stuff. It is not difficult at all, but ignorance will get you in trouble.
If you are only spray painting for looks, I would recommend just masking off the areas you don't want painted instead of a complete disassembly.
Make sure to post pictures of your work too. We all like to see...