One: polymer coatings on steel cases cannot "build up" in a chamber. Neither, for that matter can lacquer. Technically, the "lacquer" used on rifle cases has been a synthetic polymer rather than an organic lacquer for many decades. Do an experiment: get a few spent steel cases (AK cases will do), and include a few poly cases and a few lacquered cases. Without burning yourself, hold one of each in a flame and watch what happens. Neither will "soften," "drip off," or otherwise leave any sort of residue. Both will eventually burn with little ash or smoke. The temperature needed to burn off the coatings is higher than the ignition point of most powders, so if you don't get a gun hot enough to cook off rounds, you are not going to have coatings leave gunk in your chamber. See Two and Three below...
Two: the issue with steel cased ammunition in ARs is that steel is not as springy as brass, and with the small diameter of the .223/5.56mm neck, the case doesn't seal the chamber as well as brass cases do when fired.
Three: the above leads to leakage of powder gases into the forward part of the chamber, which, if allowed to build up, will (not just "can") cause problems with stuck cases. NOT coatings, NOT a Commie conspiracy, just powder residue that doesn't get cleaned away.
Four: if you're intending to put together a "steel-only" AR, invest in some quality bore and chamber brushes, and practice cleaning the chamber and barrel. A clean rifle will have fewer stoppages of any kind, for any reason, and especially will handle steel cases better than a filthy gun.
Five: the reason you don't hear about AKs having stuck case problems with steel cased ammunition is two-fold. First, the 7.62x39 (and the 5.45x39, for that matter) were designed with a significantly tapered case to facilitate both feeding and extraction. Second, AKs almost always have chrome lined chambers and bores, which reduces the stickiness of the crap that will inevitably build up in the gun.
Advice: if you really want a "this gun can eat the crappiest ammo I can feed it" build, start looking at Melonited barrels. Melonite makes surfaces substantially slicker than chrome plating, which will make cleaning easier and reduce stoppages even in a badly neglected gun. You'll also have to decide if you want to run truly crappy ammo, such as TulAmmo, and make allowances for varying gas pressure levels; you may need to buy multiple buffers to tune the rifle for good, poor, and bad ammo.
Good luck.