If you zero at 30 yds., you will be 1.6" high at 100, back to zero at 157 and 2.7" low at 200. So, for iron sights, you just put it on the spot out to 200, with no hold over or under. If you were to zero at 100, you would be 5.6" low at 200. Since you want to be able to shoot quickly and accurately from 25 to 200, I'd say zero at 30. You'll have to check it at 100 and make any adjustments necessary. It's also a lot easier to see your target for sighting-in purposes at the shorter distance. 25 yds is a little extreme, making you 2.4" high at 100, coming back to zero at 186 yds. and only 0.9" low at 200.
This was done on the ballistic calculator on the Norma Ammunition site, using the 'design your own' button (they don't list any 7.62 x 39). I put in a ballistic coefficient of .350 and a weight of 124 grains, with a velocity of 2399 fps. Try it out - it's fun.