Those look like good picks for lower parts.
Since you already found PSA, I would recommend looking on there for a stock. They sell complete assemblies that have the extension, buffer, action spring, castle nut, end plate, and stock all included for a fair price; they just take forever to ship.
I would recommend getting a prebuilt upper as that eliminates the need to build and barrel the upper receiver. But that in itself is not all that hard to do. Either way, you can still change out handguards and customize it to your liking.
My recommendation for chambering is to go with the 5.56. They are built to take the higher pressures exerted by the 5.56 and can fire both 5.56 and .223 safely. The throat of the chamber is also longer in 5.56 so that it can take the heavier 72 grain loads with out the bullet touching the rifling prior to firing. There is also a .223 Wylde chamber that was made to get the most out of match ammo. Incidentally, it is also strong enough to handle 5.56 just like a true 5.56 chamber.
What ever you do, do not put large amounts of 5.56 through a .223 chamber. That will lead to barrel and chamber damage as it was not designed to take those pressures.