E85 gas is up to 85% ethanol. E10 is normal pump gas and containes up to 10% ethanol.
Don’t stress it. Ethanol isn’t the scary boogeyman the internet wants you to think it is. All gas goes bad given enough exposure to air and time. Ethanol in the gas will help keep your fuel system cleaner due to the solvent action of ethanol.
I run E10 gas in everything without a single issue. It won’t hurt your generator. Your generator won’t run properly (or probably won’t run at all) on E85 which is why the manufacturer says not to use it.
Since you have a dual fuel, you have the best generator fuel available to you. If I was you, I’d run primarily on propane with gas as the backup.
NATO cans are excellent and E10 gas will keep for years (yes years) if stored in a NATO can. Just make sure they are real NATO cans and not Chinese knockoffs.
I’d run a quality synthetic. There is a lot of emotional bullshit surrounding people’s opinions on oil. Personally, I’d run Mobil 1 Extended Performance oil and not worry about it. Someone will probably come along and be horrified at my oil recommendation. Funny thing is, if I couldn’t run Mobil 1 EP for any reason, I’d pick one of the other quality oils out there. There are plenty of good ones to choose from.