1) There is no such law in PA requiring the firearm or ammunition to be inaccessible to the driver or anyone else in the vehicle. If you lack the PA "license to carry firearms", you can have the unloaded firearm on the seat next to you if going to the range and other places allowed by law.
Transporting unloaded firearm;
Range: (4) Any persons engaged in target shooting with a firearm, if such persons are at or are going to or from their places of assembly or target practice and if, while going to or from their places of assembly or target practice, the firearm is not loaded.
Gunsmith, gun dealer, etc: (8) Any person while carrying a firearm which is not loaded and is in a secure wrapper from the place of purchase to his home or place of business, or to a place of repair, sale or appraisal or back to his home or place of business, or in moving from one place of abode or business to another or from his home to a vacation or recreational home or dwelling or back, or to recover stolen property under section 6111.1(b)(4) (relating to Pennsylvania State Police), or to a place of instruction intended to teach the safe handling, use or maintenance of firearms or back or to a location to which the person has been directed to relinquish firearms under 23 Pa.C.S. § 6108 (relating to relief) or back upon return of the relinquished firearm or to a licensed dealer's place of business for relinquishment pursuant to 23 Pa.C.S. § 6108.2 (relating to relinquishment for consignment sale, lawful transfer or safekeeping) or back upon return of the relinquished firearm or to a location for safekeeping pursuant to 23 Pa.C.S. § 6108.3 (relating to relinquishment to third party for safekeeping) or back upon return of the relinquished firearm.
2) There is no such law in PA requiring the ammunition to be in a closed container. The only requirement for transporting a firearm and ammunition without having a LTCF, is that firearms that use a magazine cannot have the firearm and loaded magazine in the same compartment, ie, touching. If the magazine is in a pouch with a secure flap, then that would be considered a separate compartment and fall within the legal requirements for transportation. If I have my unloaded handgun in a soft or hard case, I can have the ammunition in a coffee can.
Loaded definition: "Loaded." A firearm is loaded if the firing chamber, the nondetachable magazine or, in the case of a revolver, any of the chambers of the cylinder contain ammunition capable of being fired. In the case of a firearm which utilizes a detachable magazine, the term shall mean a magazine suitable for use in said firearm which magazine contains such ammunition and has been inserted in the firearm or is in the same container or, where the container has multiple compartments, the same compartment thereof as the firearm. If the magazine is inserted into a pouch, holder, holster or other protective device that provides for a complete and secure enclosure of the ammunition, then the pouch, holder, holster or other protective device shall be deemed to be a separate compartment.