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Having shot both in the same session, I would jump on the Buckmark 9/10. If you just can't or won't suppress, the Buckmark takes it every time. The Walther does a good job emulating a combat handgun but without the polish that I felt was needed.
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Interestingly enough, the comment about the Walther P22 emulating a combat handgun is intriguing. What are you thinking there?
I have an early production P22 and a 5.5in 'bull-barrel' Buckmark. And I have a lot of 'combat handguns.' I don't see the P22 as related to 'combat handguns' at all. Were you thinking of the Walther PPQ in .22LR instead? I have one of those too, and it's a great handgun, and could be considered as 'emulating a combat handgun.'
Of the two mentioned by the OP, I would take the Buckmark in a flash. While there have been problems with the zinc slide of the P22 (and that bothers me. I bought the one that I have back when S&W was advertising them and selling them, and they flat out lied by claiming they had a steel slide.), I have had no problems with mine (the original early magazines even work well with mine). Still, if I wanted a gun like that today, I'd snap up the Ruger SR22 well before a Walther P22.
It somewhat depends on what you want the gun to do for you (well, it almost always depends on that).
The Buckmark I have is much bigger than the P22 and has been completely reliable. And, especially since I have big hands, it feels much better in my hands (but, having said that, the Ruger SR22 and the Walther P22 feel pretty good too).
For what little it's worth...
Forrest