Let the air out of the car's tires and refill the tires with R-22 or R-134 refrigerant (make an adapter hose) until the tires are soft and look like they need air badly, but can be safely driven to a filling station. When the driver gets to the filling station, the heat generated in the drive will have caused the refrigerant's pressure to increase so the tires won't appear to need air anymore. If they're checked, they may in fact be OVER pressure, and he'll end up letting some out instead, which will make them sink even lower when they cool off.
Fun for days!
Capture some ants (preferably fire ants, if they're available) and throw them in the car
along with some food for them. Cornmeal and sugar. They'll establish an ant colony under the car's carpets.
Wear head to toe protective clothing, grab an active wasp's nest, and throw it in the car through an open window.
Wrap a coat hangar in the U-joints or around the axle shafts. Not harmful, but makes alarming noises.
Trap and release rats in the car.
CJ