What is the date on the barrel?
Armourers had sanding sticks to remove rust from the chambers, I had a 1943 03-A3 that would bulge the fired cases on one side of the case. And I think the chamber had been sanded to remove some rust.
You could also have defective ammunition that caused the case to split and rupture.
I have had many old worn milsurp rifles and simply reloaded reduced loads to put less strain on the rifle and brass.
I would test fire another brand of ammunition and see if the case ruptures, this would tell you if you have defective ammo or a oversized chamber.
I downloaded my 30-06 ammo to around 2400 fps and used 30-30 bullets for hunting deer to keep the cases from bulging.
Can you take photos of the fired primers to see how flattened they are and if they are protruding from the base of the case.
Another thing you could do is use some foam bore cleaner in the bore and let it soak overnight. Keep doing this until it no longer turns blue and you no longer have copper in the bore.
Below a 1943 No.4 British .303 Enfield rifle with a frosted and pitted bore, and one shot of foam bore cleaner would remove 95% of copper in the bore. The reason I tell you this is the ammunition used in these older milsurps had corrosive primers. And if not cleaned properly it could cause pitting in the bore that quickly picked up copper that would buildup and restrict the bore diameter. When I first cleaned my 03-A3 I actually had copper chips come out of the barrel using a very aggressive copper bore cleaner. The foam bore cleaner simply cleans the bore without having to scrub the heck out of the bore with bore brushes. The frosted and pitted bores will "eat" the copper bore brushes and give you a false copper reading.
Below one application of foam bore cleaner in a AR15 and the patch after soaking for a few hours.