Basically, you'd put the items inside the bag. You'd put the strap down inside the pouch so it lines the inside (with the edge hanging out), then put the bag in. To remove, you pull the strap hanging out and it all pops out. Small items, like NPAs and decomp needles, can go outside the pouch in the webbing. Or, you can attach a TQ holder there.
Most of these have a pretty limited capacity, mostly used for a belt option. I know HSGI has a bleeder pouch, but it doesn't have the insert, it's literally a pouch with a strap sewn to the inside (or at least, the older models do).
EDIT: Since the strap doesn't seem to be sewn down, you'd probably tie it to one of the D-rings on the bag. If there's a D-ring or similar on the inside of the pouch, you'd attach the other end there. That way you can pull it out but it's not completely separate from your body so if it pops out on accident you're not watching your medkit fall into a dark hole.