Take a good look at most factory AR barrels and the barrel shoulders look like this,
So the chamfer washer that comes with the FS, resolves the inner edge problem that is not flat on most barrel shoulders, and has the FS bearing against the outer edge of the barrel shoulder where its flat instead.
As for indexing of FS, it all about the supressor tab on it, and that you want BDC of the barrel.
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Now the down side, and since peel washers are soldered type washers, really not the best to use when you are blind pinning a FS onto a barrel for supressor. Really, since heat will be involved when you are blind pin welding, really don't want any washers or shim involved to start with (barrel shoulder steel tight to FS steel).
Myself, will face the barrel shoulder on the barrel to get it flat, take a light cut at back of threads to make sure they are not going to interfer with the FS threads (so the taper washer does not have to be used in the first place), face the back of FS as needed to get the FS to Index supressor lug BDC at 20ftlbs of torque, then drill for the blind pin channel, install the pin, tig the channel closed, then flush and re-blacken the new weld on the barrel in the end (read hard pressed to even see where the barrel was blind pinned to begin with).
To add here, looking at the direction that the washer was installed on the barrel, looks like the chamfer side what instead backwards, hence it's chamber side against the FS, and not the barrel shoulder. Also with the slight gap between the washer edge and the barrel/FS edges, looks like the blind pin is what is indexing the two together, and not the FS torqued to 20ftlbs before blind pinning. Hence if this is the case, then FS is going to be come loose on the barrel over time, which could lead to a baffle strike. So like I said, Total shite show that needs to be corrected.