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I'm building a 7.62x39 upper too, decided against the .300 blackout since ammo is so expensive and I have lots of 7.62x39 rifles and ammo. I'd like to find a good nitrided or chrome lined barrel. Most of the nitrided barrels out there are ARD barrels that most say are not truely melonited as you can scratch them very easily. I have owned ballistic advantage barrels and can attest to the durability and corrosion resistance of their nitrided barrels, wish they would start making 7.62 barrels again.
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Black Rifle Arms sells the BA 7.62x39 barrels. Ares Defense also sells a Ntiride one. I have 3 but haven't used them yet. The ARD ones probably aren't melonite, but damn I will say they work very very well. TR Enabling also sells chrome lined ones.
To date I've put together between 15-20 7.62x39 Uppers. Most of them have used Mas Defense's phosphate barrels, but they are really nice as well in my opinion. Only barrels I have had issues with are Tactical Ambush (nitride as well). The gas port was way too small, and after trying to explain that issue, a barrel showed up one day with the hole redrilled. They haven't responded at all to me trying to find out if they want me to send one back or not. I haven't had a chance to use it yet, but I would say they righted a wrong and would give them another shot.
I have spent lots of money on finding what works because I believe in the round for the platform. I feel the days are over of people blaming the AR magwell or broken bolts or light strikes. I have had excellent results with new ASC and CPD mags, new bolts are made of 9310 instead of 8620 like older ones were, and enhanced firing pins are readily available as well as the ability to mod your own. I haven't shot enough rounds to know if the bolt will break, but as soon as I save up some more cabbage and get the range time, I will torture test one.
Oh and 7.62x39 ARs also make great pistols!