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Hardwood can support tons of weight. Ever see how a box truck is attached to the frame?
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Yes, wood.
Notice the dimensions of the wood?
It's a slab, not a thin wedge or spacer of soft pine.
But leveling a safe ought require a sliver, and there's not enough wood there to be stable.
They make sidewalks and streets out of concrete.
The same thing applies to a thin layer of concrete applied as a top layer on a sidewalk - it's not stable as a thin layer.
A safe doesn't weigh a lot compared to the compressive forces supplied by the bolts to the floor, and dogging the attachment bolts down to secure it correctly to the floor could crush the wood shims that are generally available anymore, and mostly used for things like plumbing a window or door frame in a wall.
The wood shims generally for sale at Lowes or Home Depot are cheap softwood pine with no density, unless you find hardwood shims.
Steel washers are generally available everywhere.
Depending on the quality and finish (smooth/level/flat) of the floor, and the if you work hard enough at bolting an 'inexpensive' safe to an un-even floor, you *could* rack a safe out of square and cause the door to bind.