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I have a Combat XII Pack that I use with my PC, and stand alone.
I wouldn't recommend it as a 72 hour pack, simply because it's not generally large enough for that task, depending on what you're bringing with you. It's more than adequate for a 24 hour pack, or assault pack where you want to have some extra stuff on you, but not on your PC. I put an extra medical pouch on the MOLLE, a weapon cleaning kit, extra water bottles, an extra flashlight, and a change of socks that stay in it permanently, and then add in anything extra I need for what I'm doing in particular in the main compartment. Then I can add in the extra magazines in the top part, if I need to. Or just more water bottles.
If you tried to put in enough food and water and some sort of shelter/sleep system in it, and everything else you need for 72 hours of sustainment, you'd run out of room very quickly.
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I, too, have an Ares Armor Combat XII pack, and agree with what my brother of another mother said. It is not designed as a 72-hour pack. It is designed as a "last hundred yards" pack. As in, those few items you'll need for the last hundred yards of a movement to contact or raid-things like water, ammo, comms, a few light snacks, that sort of thing. It's designed for an individual to carry a minimal amount of items which serve a distinct purpose. The pack is purposefully designed not to be big enough to carry so much that the person tries to carry too much.
I have mine set up this way:
Main Compartment:
-2 hydration bladders
-poncho
Large Outside Compartment:
-2 broken down MRE's
Small outside compartment:
-extra CAT-T TQ
-Surefire spare battery/bulb carrier
-a few chem lights of various colors
Top Mag pouches:
-6 PMAGs
left and right side MOLLE:
-1 smoke grenade pouch and M-18 each
back MOLLE:
-Eagle Admin panel w/ NFA paperwork and a Glock 19 mag
-mag pouch w/ G-19 mag (total of two pistol mags on it)
-2 TT 6-round shotgun panels (assorted shotgun ammo-00Buck, slugs, LL)
Basically, I use mine as a reload/sustainment pack, and carry ammo appropriate for whichever gun I might have on me, as well as water and emergency food.