There wouldn't be anything odd about two sizes of 30 caliber barrels. American 30 cal. is .308 dia. while the Russian is .311. I'm sure they have a system that keeps them from getting mixed up and I'm sure they are clearly marked.
I couldn't find anything specific to the VEPR's twist rate but the cartridge uses a 1 in 9 1/2'' twist. It would be easy to find out for sure (I don't have mine yet). Put a cleaning rod with a tight fitting patch down the bore like you're cleaning it, push it into the receiver then start pulling it back out. When it's into the rifling make a mark on the rod at the top at the muzzle. Slowly pull the rod out watching that mark, when it makes one turn make another mark on the rod. Pull it out and measure the distance between those marks and you'll have your twist rate.
1 in 9 1/2'' seems a little fast for 30 cal. but the 30-06 uses a 1 in 10'' so I guess it makes sense.
As far as what bullet is most accurate, I couldn't tell you for sure, again, I don't have mine yet, but you have a lot of bullet choices. Anything from 140gr to 200+gr. Most commercial ammo is a 150gr bullet but it seems Mosin's favor something around 170gr, at least my most accurate one does. I have a real good load made with a 174gr Sierra Matchking, maybe that would be a good place to start.
When mine comes in I'm going to try that load, see how it does then make adjustments if needed.
Good luck.
ETA: About 2 hrs ago I got a call from my LGS saying my rifle is there ! I hauled ass down there and picked it up. Wow, beautiful rifle, well built and nicely finished. I like it !
I checked the twist rate and it's 1 in 10 3/4''.