I try to stay around 225 with ribs. Internal temp is a hard thing to do with them, since the bone temp can influence what you read on the meat. Grab a hold of them with some tongs and bend, if the meat cracks and tears, you're good.
Time, usually something like 5-6 hours for a slab of spare ribs or St. Louis cut, 3-4 hours for baby backs.
Rubs, I really like Meathead's Memphis Dust from Amazingribs.com:
3/4 cup of firmly packed brown sugar
3/4 cup of white sugar
1/2 cup of paprika
1/4 cup of garlic powder
2 tbsp each of fresh ground pepper, ginger powder, onion powder
2 tsp of ginger powder
This recipe used to have salt in it, but the creator took it out and recommends that you salt your ribs to your tastes, and I agree. I usually go with a little vegetable oil on the slab, a couple heavy pinches of kosher salt, then the rub.