1. You need a BFR as others have said. If you are only going to fly the 750 or another LSA aircraft, you will not need to get a medical.
2. You better make damn sure the 750 is legal. That it is registered, that it is in conditional (annual is for certified, but basically the same idea), and any transponder checks (if installed) have been done, and the ELT has been tested and the batteries are good.
3. Your friend is not legal to be flying anything but 103, so he sure as hell is not legal to carry PAX.
4. I'd make damn sure I was on the insurance if he has any, and if not..... Not so sure I would fly the plane.
You can get your BFR, get on his insurance (if he has any), and make sure the plane is legal and you can be PIC with his just being another guy sitting in the plane to get the experience to fly that plane. I have a buddy that does not currently have a medical and I fly with him in his Cessna 180 and 140. Another I fly him with his 210.
For insurance be a named pilot, not just 'open pilot' (google 'Subrogation'). And I would not fly it if there is no insurance unless you are willing to cut a check for what he thinks it is worth and have an umbrella policy that covers everything else. You as PIC will be held liable for any damages to people or property on the ground. So if you lose an engine and put it through a fence..... If there is no insurance, he can come after you for the cost of the plane and the guy who owns the fence can come after you for the cost of the fence. If you are "open pilot" the insurance company is there to protect HIM, not you. So the insurance company would pay for the plane and the fence and then maybe try to collect from you.
But I would double check the aircraft legality. You as PIC are responsible and held accountable if the plane's paperwork is not correct. "I don't own it" is not an excuse.