One thing to be clear on is the percent matching....there are actually 2 different percentages involved and based upon your post I suspect there may be some confusion.
Matching percentage: the percentage the employer will pay with respect to the amount the employee paid. IE, 50% match, the employer pays $1 for every $2 your wife contributes
Matching limit percentage: the percentage of the employee's pay at which the employer stops matching. Most employers stop at 5%. IE, Your wife makes $100k per year, the employer will match her contributions up to 5% of her yearly salary, or $5k.
Therefore, it's possible to have 50% matching up to 5% cap. IE, if your wife makes $100k/yr and contributes $5k, the employer will match up to $2500.
That being said, generally you should max out any matching potential if it does not jeopardize your personal finances.
If I were in your position I would stop contributions to my own 401k to allow our personal finances to accommodate a higher contribution to hers. One thing to keep in mind is the annual contribution limits laid out by the IRS (IIRC 18,500 this year). Don't allow her contributions to exceed that amount.